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Lanthan (La)

engelsk: Lanthanum
Lanthan er et kemisk grundstof i det periodiske system med kemisk symbol La og atomnummer 57 med en atomvægt på 138.905 u og er klassificeret som lanthanider og er en del af gruppen 3 (scandiumgruppe). Lanthan er fast ved stuetemperatur.

Lanthan i det periodiske system

SymbolLa
Atomnummer57
Gruppe3 (Scandiumgruppe)
Periode6
Blokd
KlassifikationLanthanider
UdseendeSilvery white
Farve Sølv
Antal protoner57 p+
Antal neutroner82 n0
Antal elektroner57 e-
Fra Wikipedia, den gratis encyklopædiLanthan (af græsk; λανθανω [lanthanō] "det der ligger skjult") er det 57. grundstof i det periodiske system: Det har det kemiske symbol La, og under normale temperatur- og trykforhold optræder stoffet som et sølvhvidt metal, der er blødt nok til at man kan skære i det med en kniv. Lanthan er et af de mest reaktive stoffer blandt de sjældne jordarter, og danner af sig selv kemiske forbindelser med kulstof, kvælstof, bor, selen, silicium, fosfor, svovl og med alle halogenerne — på grund af denne reaktionsvillighed iltes ("ruster") lanthan hurtigt hvis det kommer i kontakt med atmosfærisk luft. Lanthan angribes også af vand, men her spiller temperaturen en væsentlig rolle for reaktionshastigheden; i varmt vand forløber denne reaktion meget hurtigere end i koldt vand.

Fysiske egenskaber

Fase ved STPFast
Massefylde6.162 g/cm3
Atommasse138.905 u

Thermal properties

Smeltepunkt1193 K
919.85 °C
1687.73 °F
Kogepunkt3737 K
3463.85 °C
6266.93 °F
Fordampningsvarme399.57 kJ/mol

Atomiske egenskaber

Elektronegativitet (Pauling Scale)1.1
Elektronaffinitet53 kJ/mol
Oxidationstrin0, +1, +2, +3
(a strongly basic oxide)
Ioniseringsenergier
  1. 538.1 kJ/mol
  2. 1067 kJ/mol
  3. 1850.3 kJ/mol
  4. 4819 kJ/mol
  5. 5940 kJ/mol

Elektronkonfiguration for lanthan

Elektronkonfiguration
Kortfattet konfiguration
[Xe] 5d1 6s2
Elektronkonfiguration
Fuld konfiguration
1s2 2s2 2p6 3s2 3p6 3d10 4s2 4p6 4d10 5s2 5p6 5d1 6s2
Elektronkonfigurationsdiagram
1s2
2s22p6
3s23p63d10
4s24p64d10
5s25p65d1
6s2
Elektroner pr. Skal2, 8, 18, 18, 9, 2
Valenselektroner 2
Valency-elektroner 3
Bohrs atommodel
LanthanElectron shell for Lanthan, created by Injosoft ABLa
Figur: Skaldiagram af Lanthan (La) atom.
Orbital diagram
1s
2s2p
3s3p3d
4s4p4d
5s5p5d
6s

The history of Lanthanum

OpdagetCarl Gustaf Mosander (1838)
Navngivet afCarl Gustaf Mosander
Opdagelse af lanthan
In 1751, the Swedish mineralogist Axel Fredrik Cronstedt discovered a heavy mineral from the mine at Bastnäs, later named cerite. Thirty years later, the fifteen-year-old Wilhelm Hisinger, from the family owning the mine, sent a sample of it to Carl Scheele, who did not find any new elements within. In 1803, after Hisinger had become an ironmaster, he returned to the mineral with Jöns Jacob Berzelius and isolated a new oxide which they named ceria after the dwarf planet Ceres, which had been discovered two years earlier. Ceria was simultaneously independently isolated in Germany by Martin Heinrich Klaproth. Between 1839 and 1843, ceria was shown to be a mixture of oxides by the Swedish surgeon and chemist Carl Gustaf Mosander, who lived in the same house as Berzelius and studied under him: he separated out two other oxides which he named lanthana and didymia. He partially decomposed a sample of cerium nitrate by roasting it in air and then treating the resulting oxide with dilute nitric acid. That same year, Axel Erdmann, a student also at the Karolinska Institute, discovered lanthanum in a new mineral from Låven island located in a Norwegian fjord. Finally, Mosander explained his delay, saying that he had extracted a second element from cerium, and this he called didymium. Although he didn't realise it, didymium too was a mixture, and in 1885 it was separated into praseodymium and neodymium. Since lanthanum's properties differed only slightly from those of cerium, and occurred along with it in its salts, he named it from the Ancient Greek λανθάνειν [lanthanein] (lit. to lie hidden). Relatively pure lanthanum metal was first isolated in 1923.

Identifikatorer

List of unique identifiers for Lanthan in various chemical registry databases
CAS Number7439-91-0
ChemSpider ID22369
EC number231-099-0
PubChem CID Number23926