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Ruthenium (Ru)

engelsk: Ruthenium
Ruthenium er et kemisk grundstof i det periodiske system med kemisk symbol Ru og atomnummer 44 med en atomvægt på 101.072 u og er klassificeret som overgangsmetal og er en del af gruppen 8 (jerngruppe). Ruthenium er fast ved stuetemperatur.

Ruthenium i det periodiske system

SymbolRu
Atomnummer44
Gruppe8 (Jerngruppe)
Periode5
Blokd
KlassifikationOvergangsmetal
UdseendeSilvery white metallic
Farve Sølv
Antal protoner44 p+
Antal neutroner57 n0
Antal elektroner44 e-
Fra Wikipedia, den gratis encyklopædiRuthenium (efter Rus; latin for Rusland) er det 44. grundstof i det periodiske system: Under normale temperatur- og trykforhold optræder dette overgangsmetal som et hårdt, hvidt metal. Ruthenium udgør sammen med rhodium og palladium de lette platinmetaller. Ruthenium angribes ikke af syrer, men kan angribes af halogener ved høj temperatur, og opløses i smeltede, basiske stoffer. Stoffet reagerer med ilten i atmosfærisk luft, og danner derved rutheniumtetraoxid (RuO4).

Fysiske egenskaber

Fase ved STPFast
Massefylde12.45 g/cm3
Atommasse101.072 u

Thermal properties

Smeltepunkt2607 K
2333.85 °C
4232.93 °F
Kogepunkt4423 K
4149.85 °C
7501.73 °F
Fordampningsvarme567.77 kJ/mol

Atomiske egenskaber

Elektronegativitet (Pauling Scale)2.2
Elektronaffinitet100.96 kJ/mol
Oxidationstrin−4, −2, 0, +1, +2, +3, +4, +5, +6, +7, +8
(a mildly acidic oxide)
Ioniseringsenergier
  1. 710.2 kJ/mol
  2. 1620 kJ/mol
  3. 2747 kJ/mol

Elektronkonfiguration for ruthenium

Elektronkonfiguration
Kortfattet konfiguration
[Kr] 4d7 5s1
Elektronkonfiguration
Fuld konfiguration
1s2 2s2 2p6 3s2 3p6 3d10 4s2 4p6 4d7 5s1
Elektronkonfigurationsdiagram
1s2
2s22p6
3s23p63d10
4s24p64d7
5s1
Elektroner pr. Skal2, 8, 18, 15, 1
Valenselektroner 8
Valency-elektroner 3
Bohrs atommodel
RutheniumElectron shell for Ruthenium, created by Injosoft ABRu
Figur: Skaldiagram af Ruthenium (Ru) atom.
Orbital diagram
1s
2s2p
3s3p3d
4s4p4d
5s

The history of Ruthenium

Opdagelse og første isolationKarl Ernst Claus (1844)
Opdagelse af ruthenium
Though naturally occurring platinum alloys containing all six platinum-group metals were used for a long time by pre-Columbian Americans and known as a material to European chemists from the mid-16th century, not until the mid-18th century was platinum identified as a pure element. That natural platinum contained palladium, rhodium, osmium and iridium was discovered in the first decade of the 19th century. It is possible that the Polish chemist Jędrzej Śniadecki isolated element 44 (which he called "vestium" after the asteroid Vesta discovered shortly before) from South American platinum ores in 1807. He published an announcement of his discovery in 1808. His work was never confirmed, however, and he later withdrew his claim of discovery. Jöns Berzelius and Gottfried Osann nearly discovered ruthenium in 1827. They examined residues that were left after dissolving crude platinum from the Ural Mountains in aqua regia. Berzelius did not find any unusual metals, but Osann thought he found three new metals, which he called pluranium, ruthenium, and polinium. This discrepancy led to a long-standing controversy between Berzelius and Osann about the composition of the residues. As Osann was not able to repeat his isolation of ruthenium, he eventually relinquished his claims. In 1844, Karl Ernst Claus, a Russian scientist of Baltic German descent, showed that the compounds prepared by Gottfried Osann contained small amounts of ruthenium, which Claus had discovered the same year. Claus isolated ruthenium from the platinum residues of rouble production while he was working in Kazan University, Kazan. Choosing the name for the new element, Claus stated: "I named the new body, in honour of my Motherland, ruthenium. I had every right to call it by this name because Mr. Osann relinquished his ruthenium and the word does not yet exist in chemistry." In doing so, Claus started a trend that continues to this day - naming an element after a country.

Identifikatorer

List of unique identifiers for Ruthenium in various chemical registry databases
CAS Number7440-18-8
ChemSpider ID22390
EC number231-127-1
PubChem CID Number23950