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Compare Sodium vs Lithium

Comparing Sodium (Na) and Lithium (Li). Atomic numbers 11 and 3 with atomic masses 22.99 u and 6.938 u, classified as alkali metal and alkali metal. Below: a side-by-side comparison of their physical, atomic, electron-configuration and historical properties, including density, melting and boiling points, ionization energies, oxidation states and discovery history.

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Periodic properties of the elements

SodiumLithium
SymbolNaLi
Atomic number113
Group11
Period32
Blockss
Element categoryAlkali MetalAlkali Metal

Physical properties

SodiumLithium
Phase at STPSolidSolid
Density0.968 g/cm30.534 g/cm3
Atomic weight22.9898 u6.938 u
Melting point370.944 K
97.794 °C
208.0292 °F
453.65 K
180.5 °C
356.9 °F
Boiling point1156.09 K
882.94 °C
1621.292 °F
1603 K
1329.85 °C
2425.73 °F

Atomic properties

SodiumLithium
Electronegativity (Pauling Scale)0.930.98
Electron affinity52.867 kJ/mol59.6326 kJ/mol
Oxidation states−1, +1
(a strongly basic oxide)
+1
(a strongly basic oxide)
Ionization energies
  1. 495.8 kJ/mol
  2. 4562 kJ/mol
  3. 6910.3 kJ/mol
  4. 9543 kJ/mol
  5. 13354 kJ/mol
  6. 16613 kJ/mol
  7. 20117 kJ/mol
  8. 25496 kJ/mol
  9. 28932 kJ/mol
  10. 141362 kJ/mol
  11. 159076 kJ/mol
  1. 520.2 kJ/mol
  2. 7298.1 kJ/mol
  3. 11815 kJ/mol

Electron configuration

SodiumLithium
Shorthand configuration[Ne] 3s1 [He] 2s1
Full configuration1s2 2s2 2p6 3s1 1s2 2s1
Electrons per shell2, 8, 12, 1

History

SodiumLithium
DiscoveryHumphry Davy (1807)Johan August Arfwedson (1817)
First isolationHumphry Davy (1807)William Thomas Brande, Sir Humphrey Davy (1821)